AZ 10XT-20

! Cleanroom humidity warning !

Control of the relative humidity (RH) in photolithography zones is extremely critical. Stable and reproducible photolithography is expected within 38% to 48% RH range.

  • In case of low RH (< 38%), the resist sensitivity and development rate decreases. It is then recommended to increase the recommended exposure doses.
  • In case of high RH (> 48%), the resist adhesion decreases. It is then recommended to do an additional bake (>10 minutes @ 150°C) before loading the wafers in the HMDS or coating equipment.

Wafer surface preparation

Usually adhesion of photoresist on inorganic materials is poor resulting in losses of fine structures after development. To solve the issue, silicon wafers are generally treated using the HMDS vapor prime treatment before spincoating the photoresist. Details about the HMDS process and control can be found here: link

Assuming wafers with a clean surface free of organic contamination, the best adhesion will be obtained with the surface preparation recommended in the table:

Surface material (larger area) Vapor HMDS Plasma O2 Thermal dehydratation
Si √√
SiO2, fused silica, SiN, Si3N4 √√
Float glass, pyrex √√
Metals: Al, Au, Pt, Ti √√
Metals: Ag, Cu, Cr, Fe X √√
III/V semiconductors (GaN, GaAs) X √√

Legend: √√ Strongly recommended / √ Alternative process / … Not effective / X May affect or destroy underlaying material

Spincoating

The AZ 10XT-20 spincurve is shown below, as well as process details for both automatic and manual coating.

Available thicknesses: 2 um / 3 um / 4 um

Available recipes:

Recipe name Spin speed [rpm] Softbake time [mm:ss] PR thickness [µm] Options
C4_N_10XT_2u_EBR 3800 02:00 2 _EC, _N
C4_N_10XT_3u_EBR 1750 02:20 3 _EC, _N
C4_N_10XT_4u_EBR 1000 02:40 4 _EC, _N

Spin time is adjusted with the rotation speed. Softbake is performed at 100µm proximity. Softbake temperature is 115°C for all options.

  • Find the spin-coating speed “XXXX” [RPM] matching your target thickness from the AZ 10XT-20 spincurve.
  • When coating on wafers, use the STD_”XXXX” recipe, which includes a 500 RPM spreading step and 40 seconds of main coating step.
  • When coating on small chips, use the CHIP_”XXXX” recipe, which includes 40 seconds of main coating step and a short acceleration at the end to reduce edge bead effects.
  • Softbake temperature: 105°C
  • Softbake time: 90” + 20”/um

Exposure

The following table lists the recommend dose “to clear” for AZ 10XT-20 coated on silicon wafers. It is recommended to perform a contrast curve / exposure matrix calibration for wafers other than silicon.

Illumination:  Broadband* i-line (355-365 nm) h-line (405 nm)
Equipment:  MABA6, MA6 Gen3 (no filter) VPG 200, MA6 Gen3 (filter), MJB4  MLA 150
PR thickness [µm]  Dose [mJ/cm2]+  Dose [mJ/cm2]++  Dose [mJ/cm2]+++
2 190 175 130
3 240 220 165
4 300 270 200

* Mercury Lamp, Mask Aligner with UV400 configuration & no filter / + Based on intensity readings from Süss optometer broadband CCD / ++ Based on intensity readings from Süss optometer i-line CCD / +++ Based on MLA150 internal dose measurements

Development

The recommended developer for AZ 10XT is AZ 400K (diluted in water 1:3.5), an organic solution based upon KOH. Development with AZ 400K will result in a sharper edge profile.

IMPORTANT:
After development, it is mandatory for wafers to go through an additional rinsing step with DI water to avoid backside contamination and damage on equipments (chuck in etcher) in further processing steps. The water baths of the following wet benches can be used free of charge (5 min. billing delay after login):

Standard recipes are listed below:

Recipe name PR thickness [µm] Total contact time [s]
D4_N_10XT_2u_B
2
85
D4_N_10XT_3u_B
3
105
D4_N_10XT_4u_B
4
125

The developement consists of an initial spray dispense followed by two steps of puddle method, with intermediate DI water rinse steps. A short bake (10 sec) with large gap is used to dry the wafer backside.

  • Recommended developer: AZ 400K diluted 1 to 3.5 DI
  • Development time: 45″/um
  • Rinse: H2O 1min

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