XRD Publications

Spinel Structural Disorder Influences Solar‐Water‐Splitting Performance of ZnFe2O4 Nanorod Photoanodes.
Xiado Zhu, Néstor Guijarro,  Yongpeng Liu, Pascal Schouwink, Rebekah A. Wells, Florian Le Formal, Song Sun, Chen Gao and Kevin Sivula.
Advanced Materials 2018, ahead of print.
DOI: 10.1002/adma.201801612

Chemical transformations at the nanoscale: nanocrystal-seeded synthesis of β-Cu2V2O7 with enhanced photoconversion efficiencies.
Chethana Gadiyar, Michal Strach, Pascal Schouwink, Anna Loiudice and Raffaella Buonsanti
Chemical Science 2018, 9, pp 5658-5665.
DOI: 10.1039/C8SC01314D

Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films
Aron J. Huckaba, Alessia Senes, Sadig Aghazada, Azin Babaei, Stefan C. J. Meskers , Iwan Zimmermann, Pascal Schouwink, Natalia Gasilova, René A. J. Janssen, Henk J. Bolink and Mohammad Khaja Nazeeruddin
ACS Omega, 2018, 3 (3), pp 2673–2682
DOI: 10.1021/acsomega.8b00137

Selective growth of layered perovskite for stable and efficient photovoltaics
Kyungtaek Cho , Giulia Grancini, Yonghui Lee, Emad Oveisi, Jaehoon Ryu, Osbel Almora, Manuel Tschumi, Pascal Schouwink, Gabseok Seo, Sung Heo, Jucheol Park, Jyongsik Jang, Sanghyun Paek, Germà Garcia-Belmonte and Mohammad Khaja Nazeeruddin
Energy & Environmental Science (2018), Ahead of Print
DOI: 10.1039/C7EE03513F

Reversible Dihydrogen Activation and Hydride Transfer by a Uranium Nitride Complex
Marta Falcone, Lok Nga Poon, Farzaneh Fadaei Tirani, Marinella Mazzanti
Angewandte Chemie, International Edition (2018), Ahead of Print
10.1002/anie.201800203

Synthesis, characterization and cytotoxicity of arene–ruthenium(II) complexes with acylpyrazolones functionalized with aromatic groups in the acyl moiety
Fabio Marchetti, Riccardo Pettinari, Corrado Di Nicola, Claudio Pettinari, Jessica Palmucci, Rosario Scopelliti, Tina Riedel, Bruno Therrien, Agustin Galindo and Paul J. Dyson
Dalton Transactions (2018), 47, 868-878.
10.1039/C7DT04249C

The Many Faces of Mixed Ion perovskites: Unraveling and Understanding the Crystallization Process
Paul Gratia, Iwan Zimmermann, Pascal Schouwink, Jun-Ho Yum, Jean-Nicolas Audinot, Kevin Sivula, Tom Wirtz, and Mohammad Khaja Nazeeruddin
ACS Energy Letters (2017), 2 (12), 2686–2693.
DOI: 10.1021/acsenergylett.7b00981

Gold-Catalyzed Synthesis of 1,3-Diaminopyrazoles from 1-Alkynyltriazenes and Imines
Jeanbourquin, Loic N.; Scopelliti, Rosario; Tirani, Farzaneh Fadaei; Severin, Kay
Helvetica Chimica Acta (2017), Ahead of Print.

Approaches for selective synthesis of Ullazine donor-acceptor systems
Nikita A. Drigo, Sanghyun Paek, Aron J. Huckaba, Pascal A. Schouwink, Nouar Tabet, Mohammad K. Nazeeruddin
Chemistry – A European Journal (2017), Ahead of print.
DOI: 10.1002/chem.201704694

Organometallic Glutathione S-Transferase Inhibitors
Paunescu, Emilia; Soudani, Mylene; Martin, Paloma; Scopelliti, Rosario; Lo Bello, Mario; Dyson, Paul J.
Organometallics (2017), 36(17), 3313-3321.
DOI:10.1021/acs.organomet.7b00468

Divergent Asymmetric Synthesis of Polycyclic Compounds via Vinyl Triazenes
Kossler, David; Perrin, Florian G.; Suleymanov, Abdusalom A.; Kiefer, Gregor; Scopelliti, Rosario; Severin, Kay; Cramer, Nicolai
Angewandte Chemie, International Edition (2017), 56(38), 11490-11493.
DOI:10.1002/anie.201706013

Using predefined M3(µ3-O) clusters as building blocks for an isostructural series of metal-organic frameworks
L. Peng, M. Asgari, P. Mieville, P. Schouwink, S. Bulut, Daniel T. Sun, Z. Zhou, P. Pattison, W. vanBeek, and W. L. Queen
Appl Mater Interfaces (2017), 9(28), 23957-23966.
DOI: 10.1021/acsami.7b06041.

Towards a frustrated Lewis pair-ionic liquid system
Perrin, Florian G.; Bobbink, Felix D.; Paunescu, Emilia; Fei, Zhaofu; Scopelliti, Rosario; Laurenczy, Gabor; Katsyuba, Sergey; Dyson, Paul J.
Inorganica Chimica Acta (2017), Ahead of Print.
DOI:10.1016/j.ica.2017.07.045

Influence of the Linker Length on the Cytotoxicity of Homobinuclear Ruthenium(II) and Gold(I) Complexes
Batchelor, Lucinda K.; Paunescu, Emilia; Soudani, Mylene; Scopelliti, Rosario; Dyson, Paul J.
Inorganic Chemistry (2017), 56(16), 9617-9633.
DOI:10.1021/acs.inorgchem.7b01082

From Nano- to Micrometer Scale: The Role of Antisolvent Treatment on High Performance Perovskite Solar Cells
Paek, S.; Schouwink, P.; Athanasopoulou, E. Nefeli; Cho, K. T.; Grancini, G.; Lee, Y.; Zhang, Y.; Stellacci, F.; Nazeeruddin, Mohammad Khaja; Gao, P.
Chemistry Of Materials (2017), 29(8), 3490-3498.
DOI: 10.1021/acs.chemmater.6b05353

CO cleavage and CO2 functionalization under mild conditions by a multimetallic CsU2 nitride complex
Falcone, Marta; Chatelain, Lucile; Scopelliti, Rosario; Mazzanti, Marinella
Chimia (2017), 71(4), 209-212.
DOI:10.2533/chimia.2017.209

A Strategy to Produce High Efficiency, High Stability Perovskite Solar Cells Using Functionalized Ionic Liquid-Dopants
By Zhang, Yi; Fei, Zhaofu; Gao, Peng; Lee, Yonghui; Tirani, Farzaneh Fadaei; Scopelliti, Rosario; Feng, Yaqing; Dyson, Paul J.; Nazeeruddin, Mohammad Khaja
Advanced Materials (2017), 29(36)
DOI:10.1002/adma.201702157

Formation pathways of metal-organic frameworks proceeding through partial dissolution of the metastable phase
Anderson, Samantha L.; Gladysiak, Andrzej; Boyd, Peter G.; Ireland, Christopher P.; Mieville, Pascal; Tiana, Davide; Vlaisavljevich, Bess; Schouwink, Pascal; Van Beek, Wouter; Gagnon, Kevin J.; Smit, Berend; Stylianou, Kyriakos
Crystengcomm (2017), 19(25), 3407-3413
DOI: 10.1039/C7CE00589J

Nitrogen reduction and functionalization by a multimetallic uranium nitride complex
By Falcone, Marta; Chatelain, Lucile; Scopelliti, Rosario; Zivkovic, Ivica; Mazzanti, Marinella
Nature (2017), 547(7663), 332-335.
DOI:10.1038/nature23279

Dicationic Ruthenium(II)-Arene-Curcumin Complexes Containing Methylated 1,3,5-Triaza-7-phosphaadamantane: Synthesis, Structure, and Cytotoxicity
Pettinari, Riccardo; Condello, Francesca; Marchetti, Fabio; Pettinari, Claudio; Smolenski, Piotr; Riedel, Tina; Scopelliti, Rosario; Dyson, Paul J.
European Journal of Inorganic Chemistry (2017), 2017(22), 2905-2910.
DOI:10.1002/ejic.201700183

Ligand and Metal Based Multielectron Redox Chemistry of Cobalt Supported by Tetradentate Schiff Bases
Andrez, Julie; Guidal, Valentin; Scopelliti, Rosario; Pecaut, Jacques; Gambarelli, Serge; Mazzanti, Marinella
Journal of the American Chemical Society (2017), 139(25), 8628-8638.
DOI:10.1021/jacs.7b03604

The Intricate Structural Chemistry of MII2nLn-Type Assemblies
Cecot, Giacomo; Marmier, Mathieu; Geremia, Silvano; De Zorzi, Rita; Vologzhanina, Anna V.; Pattison, Philip; Solari, Euro; Fadaei Tirani, Farzaneh; Scopelliti, Rosario; Severin, Kay
Journal of the American Chemical Society (2017), 139(24), 8371-8381.
DOI:10.1021/jacs.7b04861

Metathesis of a UV imido complex: a route to a terminal UV sulfide
Kelly, Rory P.; Falcone, Marta; Lamsfus, Carlos Alvarez; Scopelliti, Rosario; Maron, Laurent; Meyer, Karsten; Mazzanti, Marinella
Chemical Science (2017), 8(8), 5319-5328
DOI:10.1039/C7SC01111C

Potent Prearranged Positive Allosteric Modulators of the Glucagon-like Peptide-1 Receptor
Jones, Ben J.; Scopelliti, Rosario; Tomas, Alejandra; Bloom, Stephen R.; Hodson, David J.; Broichhagen, Johannes
ChemistryOpen (2017), 6(4), 501-505.
DOI:10.1002/open.201700062

Fixation of nitrous oxide by mesoionic and carbanionic N-heterocyclic carbenes
Eymann, Leonard Y. M.; Scopelliti, Rosario; Fadaei, Farzaneh T.; Cecot, Giacomo; Solari, Euro; Severin, Kay
Chemical Communications (2017), 53(31), 4331-4334.
DOI:10.1039/C7CC01592E

Synthesis and Reactivity of 1-Allenyltriazenes
Jeanbourquin, Loic N.; Scopelliti, Rosario; Fadaei Tirani, Farzaneh; Severin, Kay
Organic Letters (2017), 19(8), 2070-2073.
DOI:10.1021/acs.orglett.7b00671

Synthesis and characterization of semiaromatic polyamides comprising benzofurobenzofuran repeating units
Cretenoud, Julien; Ozen, Bilal; Schmaltz, Thomas; Gorl, Daniel; Fabrizio, Alberto; Corminboeuf, Clemence; Fadaei Tirani, Farzaneh; Scopelliti, Rosario; Frauenrath, Holger
Polymer Chemistry (2017), 8(14), 2197-2209.
DOI:10.1039/C7PY00129K

PdII2L4-type coordination cages up to three nanometers in size
Jansze, Suzanne M.; Wise, Matthew D.; Vologzhanina, Anna V.; Scopelliti, Rosario; Severin, Kay
Chemical Science (2017), 8(3), 1901-1908.
DOI:10.1039/C6SC04732G

Nickel pincer model of the active site of lactate racemase involves ligand participation in hydride transfer
Xu, Tao; Wodrich, Matthew D.; Scopelliti, Rosario; Corminboeuf, Clemence; Hu, Xile
Proceedings of the National Academy of Sciences of the United States of America (2017), 114(6), 1242-1245.
DOI:10.1073/pnas.1616038114

A molecularly engineered hole-transporting material for efficient perovskite solar cells

Saliba, Michael; Orlandi, Simonetta; Matsui, Taisuke; Aghazada, Sadig; Cavazzini, Marco; Correa-Baena, Juan-Pablo; Gao, Peng; Scopelliti, Rosario; Mosconi, Edoardo; Dahmen, Klaus-Hermann; et al

Nature Energy (2016), 1(2), 15017.

DOI:10.1038/nenergy.2015.17

Neutral Aminyl Radicals Derived from Azoimidazolium Dyes

Eymann, Leonard Y. M.; Tskhovrebov, Alexander G.; Sienkiewicz, Andrzej; Bila, Jose L.; Zivkovic, Ivica; Roennow, Henrik M.; Wodrich, Matthew D.; Vannay, Laurent; Corminboeuf, Clemence; Pattison, Philip; et al

Journal of the American Chemical Society (2016), 138(46), 15126-15129.

DOI:10.1021/jacs.6b09124

Synthesis, Structure, and Anticancer Activity of Arene-Ruthenium(II) Complexes with Acylpyrazolones Bearing Aliphatic Groups in the Acyl Moiety

Palmucci, Jessica; Marchetti, Fabio; Pettinari, Riccardo; Pettinari, Claudio; Scopelliti, Rosario; Riedel, Tina; Therrien, Bruno; Galindo, Agustin; Dyson, Paul J.

Inorganic Chemistry (2016), 55(22), 11770-11781.

DOI:10.1021/acs.inorgchem.6b01861

Isolation of a Star-Shaped Uranium(V/VI) Cluster from the Anaerobic Photochemical Reduction of Uranyl(VI)

Chatelain, Lucile; White, Sarah; Scopelliti, Rosario; Mazzanti, Marinella

Angewandte Chemie, International Edition (2016), 55(46), 14325-14329. DOI:10.1002/anie.201608754

Crystal Engineering of Polymeric Structures with Dative Boron-Nitrogen Bonds: Design Criteria and Limitations

Luisier, Nicolas; Bally, Kevin; Scopelliti, Rosario; Fadaei, Farzaneh T.; Schenk, Kurt; Pattison, Philip; Solari, Euro; Severin, Kay

Crystal Growth & Design (2016), 16(11), 6600-6604.

DOI:10.1021/acs.cgd.6b01292

From sunscreen to anticancer agent: ruthenium(II) arene avobenzone complexes display potent anticancer activity

Pettinari, Riccardo; Marchetti, Fabio; Petrini, Agnese; Pettinari, Claudio; Lupidi, Giulio; Smolenski, Piotr; Scopelliti, Rosario; Riedel, Tina; Dyson, Paul J.

Organometallics (2016), 35(21), 3734-3742.

DOI:10.1021/acs.organomet.6b00694

Dinuclear clathrochelate complexes with pendent cyano groups as metalloligands

Marmier, Mathieu; Cecot, Giacomo; Vologzhanina, Anna V.; Bila, Jose L.; Zivkovic, Ivica; Ronnow, Henrik M.; Nafradi, Balint; Solari, Euro; Pattison, Philip; Scopelliti, Rosario; et al

Dalton Transactions (2016), 45(39), 15507-15516.

DOI:10.1039/C6DT02758J

Facile CO Cleavage by a Multimetallic CsU2 Nitride Complex

Falcone, Marta; Kefalidis, Christos E.; Scopelliti, Rosario; Maron, Laurent; Mazzanti, Marinella

Angewandte Chemie, International Edition (2016), 55(40), 12290-12294.

DOI:10.1002/anie.201606796

Large heterometallic coordination cages with gyrobifastigium-like geometry

Cecot, Giacomo; Alameddine, Bassam; Prior, Stephanie; Zorzi, Rita De; Geremia, Silvano; Scopelliti, Rosario; Fadaei, Farzaneh T.; Solari, Euro; Severin, Kay

Chemical Communications (2016), 52(75), 11243-11246.

DOI:10.1039/C6CC06066H

Direct Conversion of Mono- and Polysaccharides into 5-Hydroxymethylfurfural Using Ionic-Liquid Mixtures

Siankevich, Sviatlana; Fei, Zhaofu; Scopelliti, Rosario; Jessop, Philip G.; Zhang, Jiaguang; Yan, Ning; Dyson, Paul J.

FChemSusChem (2016), 9(16), 2273.

DOI:10.1002/cssc.201601096

A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions

Di Franco, Thomas; Stojanovic, Marko; Keller, Sebastien Carlos; Scopelliti, Rosario; Hu, Xile

Helvetica Chimica Acta (2016), 99(11), 830-847.

DOI:10.1002/hlca.201600165

p,t-[Ru(CO)(PR3)(tren)]2+ [R = Ph or p-tol; tren = tris(2-aminoethyl)amine], Ru(II) complexes bearing a simple tripodal tetradentate amine: synthesis, characterization, and antimicrobial activity

Fagundes, Francisco D.; Reis, John D.; Appelt, Patricia; Cavarzan, Deividi A.; Murakami, Fabio S.; Scopelliti, Rosario; Dyson, Paul J.; De Araujo, Marcio P.

Journal of Coordination Chemistry (2016), 69(18), 2637-2646.

DOI:10.1080/00958972.2016.1211642

Functionalized Ionic (Poly)Styrenes and their Application as Catalysts in the Cycloaddition of CO2 to Epoxides

Bobbink, Felix D.; Fei, Zhaofu; Scopelliti, Rosario; Das, Shoubhik; Dyson, Paul J.

Helvetica Chimica Acta (2016), 99(11), 821-829.

DOI:10.1002/hlca.201600112

Divergent Reactivity of Thioalkynes in Lewis Acid Catalyzed Annulations with Donor-Acceptor Cyclopropanes

Racine, Sophie; Hegedues, Bence; Scopelliti, Rosario; Waser, Jerome

Chemistry – A European Journal (2016), 22(34), 11997-12001.

DOI:10.1002/chem.201602755

Alcohol-Induced C-N Bond Cleavage of Cyclometalated N-Heterocyclic Carbene Ligands with a Methylene-Linked Pendant Imidazolium Ring

Zhong, Wei; Fei, Zhaofu; Scopelliti, Rosario; Dyson, Paul J.

Chemistry – A European Journal (2016), 22(34), 12138-12144.

DOI:10.1002/chem.201602267

Direct Conversion of Mono- and Polysaccharides into 5-Hydroxymethylfurfural Using Ionic-Liquid Mixtures

Siankevich, Sviatlana; Fei, Zhaofu; Scopelliti, Rosario; Jessop, Philip G.; Zhang, Jiaguang; Yan, Ning; Dyson, Paul J.

ChemSusChem (2016), 9(16), 2089-2096.

DOI:10.1002/cssc.201600313

New Insights Into the Role of Imidazolium-Based Promoters for the Electroreduction of CO2 on a Silver Electrode

Lau, Genevieve P. S.; Schreier, Marcel; Vasilyev, Dmitry; Scopelliti, Rosario; Gratzel, Michael; Dyson, Paul J.

Journal of the American Chemical Society (2016), 138(25), 7820-7823.

DOI:10.1021/jacs.6b03366

Synthesis and reactivity of a terminal uranium(IV) sulfide supported by siloxide ligands

Andrez, Julie; Pecaut, Jacques; Scopelliti, Rosario; Kefalidis, Christos E.; Maron, Laurent; Rosenzweig, Michael W.; Meyer, Karsten; Mazzanti, Marinella

Chemical Science (2016), 7(9), 5846-5856.

DOI:10.1039/C6SC00675B

Surface functionalization of dinuclear clathrochelates via Pd-catalyzed cross-coupling reactions: facile synthesis of polypyridyl metalloligands

Marmier, Mathieu; Cecot, Giacomo; Curchod, Basile F. E.; Pattison, Philip; Solari, Euro; Scopelliti, Rosario; Severin, Kay

Dalton Transactions (2016), 45(20), 8422-8427.

DOI:10.1039/C6DT01288D

Carboxylic Acid Functionalized Clathrochelate Complexes: Large, Robust, and Easy-to-Access Metalloligands

Marmier, Mathieu; Wise, Matthew D.; Holstein, Julian J.; Pattison, Philip; Schenk, Kurt; Solari, Euro; Scopelliti, Rosario; Severin, Kay

Inorganic Chemistry (2016), 55(8), 4006-4015.

DOI:10.1021/acs.inorgchem.6b00276

A Functional Model of [Fe]-Hydrogenase

Xu, Tao; Yin, Chih-Juo Madeline; Wodrich, Matthew D.; Mazza, Simona; Schultz, Katherine M.; Scopelliti, Rosario; Hu, Xile

Journal of the American Chemical Society (2016), 138(10), 3270-3273.

DOI:10.1021/jacs.5b12095

High-Performance Perovskite Solar Cells with Enhanced Environmental Stability Based on Amphiphile-Modified CH3NH3PbI3

Bi, Dongqin; Gao, Peng; Scopelliti, Rosario; Oveisi, Emad; Luo, Jingshan; Graetzel, Michael; Hagfeldt, Anders; Nazeeruddin, Mohammad Khaja

Advanced Materials (2016), 28(15), 2910-2915.

DOI:10.1002/adma.201505255

Synthesis and Structure of Nitride-Bridged Uranium(III) Complexes

Chatelain, Lucile; Scopelliti, Rosario; Mazzanti, Marinella

Journal of the American Chemical Society (2016), 138(6), 1784-1787.

DOI:10.1021/jacs.5b12620

Ligand Aspect Ratio as a Decisive Factor for the Self-Assembly of Coordination Cages

Jansze, Suzanne M.; Cecot, Giacomo; Wise, Matthew D.; Zhurov, Konstantin O.; Ronson, Tanya K.; Castilla, Ana M.; Finelli, Alba; Pattison, Philip; Solari, Euro; Scopelliti, Rosario; et al

Journal of the American Chemical Society (2016), 138(6), 2046-2054.

DOI:10.1021/jacs.5b13190

Nonsteroidal Anti-inflammatory-Organometallic Anticancer Compounds

Paunescu, Emilia; McArthur, Sarah; Soudani, Mylene; Scopelliti, Rosario; Dyson, Paul J.

Inorganic Chemistry (2016), 55(4), 1788-1808.

DOI:10.1021/acs.inorgchem.5b02690

Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides

Perez Garcia, Pablo M.; Di Franco, Thomas; Epenoy, Alexandre; Scopelliti, Rosario; Hu, Xile

ACS Catalysis (2016), 6(1), 258-261.

DOI:10.1021/acscatal.5b02324

Supramolecular gels based on boronate esters and imidazolyl donors

Luisier, N.; Scopelliti, R.; Severin, K.

Soft Matter (2016), 12(2), 588-593

DOI:10.1039/C5SM02298C