Journal Articles
2024
SOMOphilic alkyne vs radical-polar crossover approaches: The full story of the azido-alkynylation of alkenes
Beilstein Journal Of Organic Chemistry
2024-04-03
Vol. 20 , p. 701-713.DOI : 10.3762/bjoc.20.64
Benzylic C(sp3)-H Azidation: Copper vs Iron Catalysis
Helvetica Chimica Acta
2024-03-04
DOI : 10.1002/hlca.202400004
Quantitative Description of Metal Center Organization and Interactions in Single-Atom Catalysts (Adv. Mater. 5/2024)
Advanced Materials
2024-02-01
Vol. 36 , num. 5.DOI : 10.1002/adma.202470038
Interrupted Polonovski Strategy for the Synthesis of Functionalized Amino Acids and Peptides
Organic Letters
2024-01-05
Vol. 26 , num. 2, p. 456-460.DOI : 10.1021/acs.orglett.3c03603
2023
Cysteine-Cysteine Cross-Conjugation of both Peptides and Proteins with a Bifunctional Hypervalent Iodine-Electrophilic Reagent
Chemistry-A European Journal
2023-10-30
DOI : 10.1002/chem.202302689
Synthesis of Fluorescent Cyclic Peptides via Gold(I)-Catalyzed Macrocyclization
Journal of the American Chemical Society
2023
Vol. 145 , num. 49, p. 26525-26531.DOI : 10.1021/jacs.3c09261
Photocatalyzed [2σ + 2σ] and [2σ + 2π] Cycloadditions for the Synthesis of Bicyclo[3.1.1]heptanes and 5- or 6-Membered Carbocycles
Journal of the American Chemical Society
2023
Vol. 145 , num. 46, p. 25411-25421.DOI : 10.1021/jacs.3c09789
Acyl-Ethynylbenziodoxolone (acyl-EBX): Access to Ketene Dithioarylacetals
Organic Letters
2023
Vol. 25 , num. 41, p. 7535-7539.DOI : 10.1021/acs.orglett.3c02869
One-pot synthesis of functionalized bis(trifluoromethylated)benziodoxoles from iodine(i) precursors
Chemical Communications
2023
Vol. 59 , num. 84, p. 12637-12640.DOI : 10.1039/D3CC04525K
Semipinacol Rearrangement of Cyclopropenylcarbinols for the Synthesis of Highly Substituted Cyclopropanes
Organic Letters
2023
Vol. 25 , num. 38, p. 6999-7003.DOI : 10.1021/acs.orglett.3c02543
Iron-Catalyzed Synthesis of α-Azido α-Amino Esters via the Alkylazidation of Alkenes
Organic Letters
2023
Vol. 25 , num. 37, p. 6791-6795.DOI : 10.1021/acs.orglett.3c02153
Photochemical [2+2] Cycloaddition of Alkynyl Boronates
Chemistry – A European Journal
2023
p. e202301650.DOI : 10.1002/chem.202301650
Copper (I)‐BOX Catalyzed Asymmetric 3‐Component Reaction for the Synthesis of Trifluoromethylated Propargylic Ethers and Anilines**
Angewandte Chemie International Edition
2023
Vol. 62 , num. 32, p. e202305776.DOI : 10.1002/anie.202305776
Azido-alkynylation of alkenes through radical-polar crossover
Chemical Science
2023-08-11
Vol. 14 , p. 9452-9460.DOI : 10.1039/d3sc03309k
Peptide-Hypervalent Iodine Reagent Chimeras: Enabling Peptide Functionalization and Macrocyclization
Angewandte Chemie-International Edition
2023-07-07
Vol. 62 , num. 33, p. e202306036.DOI : 10.1002/anie.202306036
Synthesis of Trifluoromethylated Alkenes: Hypervalent Iodine Meets High-Valent Copper
Angewandte Chemie-International Edition
2023-07-10
Vol. 62 , num. 33, p. e202306128.DOI : 10.1002/anie.202306128
Sustainable production of chemicals
Chimia
2023-03-01
Vol. 77 , num. 3, p. A101-A101.Synthesis of propargyl silanes from terminal alkynes via a migratory Sonogashira reaction
Chemical Communications
2023-05-31
Vol. 59 , num. 51, p. 7931-7934.DOI : 10.1039/d3cc01847d
Donor-Acceptor Aminocyclobutane Monoesters: Synthesis and Silylium-Catalyzed (4+2) Annulation with Indoles
Angewandte Chemie-International Edition
2023-05-12
DOI : 10.1002/anie.202302420
2022
Exploring Photoredox-Catalyzed (Re)functionalizations with Core-Modified Benziodoxolones
Helvetica Chimica Acta
2022-11-21
p. e202200161.DOI : 10.1002/hlca.202200161
Tyrosine bioconjugation with hypervalent iodine
Chemical Science
2022-10-12
Vol. 13 , p. 12808-12817.DOI : 10.1039/d2sc04558c
Substrate-controlled C-H or C-C alkynylation of cyclopropanes: generation of aryl radical cations by direct light activation of hypervalent iodine reagents
Chemical Science
2022-10-12
Vol. 13 , p. 12831-12839.DOI : 10.1039/d2sc04344k
Copper-Catalyzed Alkynylation of Hydrazides: An Easy Access to Functionalized Azadipeptides
Organic Letters
2022-09-06
Vol. 24 , num. 36, p. 6614-6618.DOI : 10.1021/acs.orglett.2c02625
(4+3) Annulation of Donor-Acceptor Cyclopropanes and Azadienes: Highly Stereoselective Synthesis of Azepanones
Angewandte Chemie-International Edition
2022-07-28
p. e202209006.DOI : 10.1002/anie.202209006
Pd(II)-Catalyzed Aminoacetoxylation of Alkenes Via Tether Formation
Organic Letters
2022-07-11
Vol. 24 , p. 5068-5072.DOI : 10.1021/acs.orglett.2c01838
Palladium-Catalyzed trans-Hydroalkoxylation: Counterintuitive Use of an Aryl Iodide Additive to Promote C-H Bond Formation
Acs Catalysis
2022-06-13
DOI : 10.1021/acscatal.2c01809
Synthesis of polycyclic aminal heterocycles via decarboxylative cyclisation of dipeptide derivatives
Chemical Communications
2022-02-15
Vol. 58 , num. 21, p. 3473-3476.DOI : 10.1039/d2cc00167e
N-Terminal Selective C-H Azidation of Proline-Containing Peptides: a Platform for Late-Stage Diversification
Chemistry-A European Journal
2022-02-23
p. e202200368.DOI : 10.1002/chem.202200368
Asymmetric Cyclopropanation and Epoxidation via a Catalytically Formed Chiral Auxiliary
Angewandte Chemie-International Edition
2022-02-01
p. e202113925.DOI : 10.1002/anie.202113925
2021
Tosyloxybenziodoxolone: A Platform for Performing the Umpolung of Alkynes in One-Pot Transformations
Organic Letters
2021-12-13
Vol. 24 , num. 1, p. 142-146.DOI : 10.1021/acs.orglett.1c03771
Direct Photoexcitation of Ethynylbenziodoxolones: An Alternative to Photocatalysis for Alkynylation Reactions**
Angewandte Chemie-International Edition
2021-09-21
Vol. 60 , num. 44, p. 23827-23834.DOI : 10.1002/anie.202110257
Cu(I)-Catalyzed gem-Aminoalkynylation of Diazo Compounds: Synthesis of Fluorinated Propargylic Amines
Journal Of Organic Chemistry
2021-08-06
Vol. 86 , num. 15, p. 10928-10938.DOI : 10.1021/acs.joc.1c01423
Diamine Synthesis via the Nitrogen-Directed Azidation of sigma- and pi-C-C Bonds
Journal Of The American Chemical Society
2021-08-11
Vol. 143 , num. 31, p. 11969-11975.DOI : 10.1021/jacs.1c06700
Inhibition of Thiol‐Mediated Uptake with Irreversible Covalent Inhibitors
Helvetica Chimica Acta
2021-07-06
Vol. 104 , p. e2100085.DOI : 10.1002/hlca.202100085
Synthesis of Quinolines via the Metal-free Visible-Light-Mediated Radical Azidation of Cyclopropenes
Organic Letters
2021-07-16
Vol. 23 , num. 14, p. 5435-5439.DOI : 10.1021/acs.orglett.1c01775
Amphiphilic Iodine(III) Reagents for the Lipophilization of Peptides in Water
Angewandte Chemie-International Edition
2021-07-12
Vol. 60 , p. 17963-17968.DOI : 10.1002/anie.202106458
Solar and Visible Light Assisted Peptide Synthesis
Synthesis-Stuttgart
2021-07-01
Vol. 53 , num. 13, p. A112-A116.Structure and Reactivity of N-Heterocyclic Alkynyl Hypervalent Iodine Reagents
Chemistry-A European Journal
2021-06-04
Vol. 27 , p. 10979-10986.DOI : 10.1002/chem.202101475
Catalytic (3+2) annulation of donor-acceptor aminocyclopropane monoesters and indoles
Chemical Science
2021-05-05
Vol. 12 , p. 8706-8712.DOI : 10.1039/d1sc01127h
Cys-Cys and Cys-Lys Stapling of Unprotected Peptides Enabled by Hypervalent Iodine Reagents
Angewandte Chemie-International Edition
2021-01-15
Vol. 60 , num. 16, p. 9022-9031.DOI : 10.1002/anie.202014511
Small peptide diversification through photoredox-catalyzed oxidative C-terminal modification
Chemical Science
2021-01-07
Vol. 12 , num. 7, p. 2467-2473.DOI : 10.1039/D0SC06180H
2020
Low‐Temperature Intramolecular [4+2] Cycloaddition of Allenes with Arenes for the Synthesis of Diene Ligands
Angewandte Chemie International Edition
2020-11-20
Vol. 60 , num. 10, p. 5475-5481.DOI : 10.1002/anie.202012299
Azide Radical Initiated Ring Opening of Cyclopropenes Leading to Alkenyl Nitriles and Polycyclic Aromatic Compounds
Angewandte Chemie International Edition
2020-11-18
Vol. 60 , num. 8, p. 4075-4079.DOI : 10.1002/anie.202013516
Synthesis of Thiochromans via [3+3] Annulation of Aminocyclopropanes with Thiophenols
Organic Letters
2020-11-20
Vol. 22 , num. 22, p. 9123-9127.DOI : 10.1021/acs.orglett.0c03528
Photocatalytic Umpolung of N- and O-substituted alkenes for the synthesis of 1,2-amino alcohols and diols
Chemical Science
2020-11-07
Vol. 11 , num. 41, p. 11274-11279.DOI : 10.1039/d0sc03655b
Enantioselective Carboetherification/Hydrogenation for the Synthesis of Amino Alcohols via a Catalytically Formed Chiral Auxiliary
Journal Of The American Chemical Society
2020-10-14
Vol. 142 , num. 41, p. 17334-17339.DOI : 10.1021/jacs.0c09177
Ori-Pixel, a Multi-DoFs Origami Pixel for Modular Reconfigurable Surfaces
Ieee Robotics And Automation Letters
2020-10-01
Vol. 5 , num. 4, p. 6988-6995.DOI : 10.1109/LRA.2020.3028054
Photochemical Functionalization of Heterocycles with EBX Reagents: C-H Alkynylation versus Deconstructive Ring Cleavage
Chemistry-A European Journal
2020-08-27
Vol. 26 , p. 14453-14460.DOI : 10.1002/chem.202002868
Polynomial Evaluation on Superscalar Architecture, Applied to the Elementary Function e(x)
Acm Transactions On Mathematical Software
2020-09-01
Vol. 46 , num. 3, p. 28.DOI : 10.1145/3408893
Access to Vinyl Ethers and Ketones with Hypervalent Iodine Reagents as Oxy-Allyl Cation Synthetic Equivalents
Angewandte Chemie-International Edition
2020-06-16
Vol. 59 , p. 18256-18260.DOI : 10.1002/anie.202006707
Oxidative Fluorination of Cyclopropylamides through Organic Photoredox Catalysis
Angewandte Chemie-International Edition
2020-06-17
Vol. 59 , p. 16420-16424.DOI : 10.1002/anie.202007864
Three-Component Reaction for the Synthesis of Highly Functionalized Propargyl Ethers
Chemistry-A European Journal
2020-03-18
Vol. 26 , p. 10199-10204.DOI : 10.1002/chem.202001317
Copper-Catalyzed Oxyvinylation of Diazo Compounds
Organic Letters
2020-05-01
Vol. 22 , num. 10, p. 3884-3889.DOI : 10.1021/acs.orglett.0c01150
Triazene-Activated Donor–Acceptor Cyclopropanes: Ring-Opening and (3 + 2) Annulation Reactions
Organic Letters
2020-05-26
Vol. 22 , p. 4517-4522.DOI : 10.1021/acs.orglett.0c01527
Ethynylation of Cysteine Residues: From Peptides to Proteins in Vitro and in Living Cells
Angewandte Chemie-International Edition
2020-03-31
Vol. 59 , p. 10961-10970.DOI : 10.1002/anie.202002626
2019
One-Pot Synthesis of 1-[(Triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one (TIPS-EBX): Process Safety Assessment and Impact of Impurities on Product Stability
Organic Process Research & Development
2019-12-24
Vol. 24 , num. 1, p. 106-110.DOI : 10.1021/acs.oprd.9b00498
Copper-Catalyzed Oxyalkynylation of C-S Bonds in Thiiranes and Thiethanes with Hypervalent Iodine Reagents
Organic Letters
2019-12-31
Vol. 22 , num. 2, p. 422-427.DOI : 10.1021/acs.orglett.9b04157
Synthesis of bicyclo[3.1.0]hexanes by (3+2) annulation of cyclopropenes with aminocyclopropanes
Chemical Science
2019-12-14
Vol. 10 , num. 46, p. 10716-10722.DOI : 10.1039/c9sc03790j
Alkynylation of radicals: spotlight on the “Third Way” to transfer triple bonds
Chemical Science
2019-10-21
Vol. 10 , num. 39, p. 8909-8923.DOI : 10.1039/c9sc03033f
1,3-Difunctionalization of Aminocyclopropanes via Dielectrophilic Intermediates
Angewandte Chemie-International Edition
2019-09-23
Vol. 58 , num. 39, p. 13880-13884.DOI : 10.1002/anie.201907060
Palladium-Catalyzed Carboxy-Alkynylation of Propargylic Amines Using Carbonate Salts as Carbon Dioxide Source
European Journal Of Organic Chemistry
2019-09-01
Vol. 2019 , num. 31-32, p. 5183-5186.DOI : 10.1002/ejoc.201900500
An Alternative One-Electron Oxidation Strategy to Access Hypervalent Iodine Reagents
Chem
2019-09-12
Vol. 5 , num. 9, p. 2287-2289.DOI : 10.1016/j.chempr.2019.08.005
Ethynylbenziodazolones (EBZ) as Electrophilic Alkynylation Reagents for the Highly Enantioselective Copper-Catalyzed Oxyalkynylation of Diazo Compounds
Chemistry-A European Journal
2019-04-08
Vol. 25 , num. 40, p. 9522-9528.DOI : 10.1002/chem.201900950
“Doubly Orthogonal” Labeling of Peptides and Proteins
Chem
2019-08-08
Vol. 5 , num. 8, p. 2243-2263.DOI : 10.1016/j.chempr.2019.06.002
C-Terminal Bioconjugation of Peptides through Photoredox Catalyzed Decarboxylative Alkynylation
Angewandte Chemie-International Edition
2019-04-18
Vol. 58 , num. 24, p. 8182-8186.DOI : 10.1002/anie.201901922
Stereoselective synthesis of alkyl-, aryl-, vinyl- and alkynyl-substituted Z-enamides and enol ethers
Chemical Science
2019-03-21
Vol. 10 , num. 11, p. 3223-3230.DOI : 10.1039/c8sc05573d
Metal-Free Electrophilic Alkynylation of Sulfenate Anions with Ethynylbenziodoxolone Reagents
Journal Of Organic Chemistry
2019-03-15
Vol. 84 , num. 6, p. 3687-3701.DOI : 10.1021/acs.joc.9b00050
Palladium-Catalyzed Carbo-Oxygenation of Propargylic Amines using in Situ Tether Formation
Chemistry-A European Journal
2019-02-26
Vol. 25 , num. 12, p. 3010-3013.DOI : 10.1002/chem.201900020
Revisiting the Urech Synthesis of Hydantoins: Direct Access to Enantiopure 1,5-Substituted Hydantoins Using Cyanobenziodoxolone
Organic Letters
2019-01-18
Vol. 21 , num. 2, p. 524-528.DOI : 10.1021/acs.orglett.8b03843
2018
Cyclic Hypervalent Iodine Reagents for Azidation: Safer Reagents and Photoredox-Catalyzed Ring Expansion
The Journal of Organic Chemistry
2018-09-15
Vol. 83 , num. 19, p. 12334-12356.DOI : 10.1021/acs.joc.8b02068
Metal-Free Oxidative Cross Coupling of Indoles with Electron-Rich (Hetero)arenes
Chemistry-A European Journal
2018-05-03
Vol. 24 , num. 40, p. 10049-10053.DOI : 10.1002/chem.201802142
Rhodium-catalyzed C–H functionalization of heteroarenes using indoleBX hypervalent iodine reagents
Beilstein Journal of Organic Chemistry
2018-05-25
Vol. 14 , p. 1208-1214.DOI : 10.3762/bjoc.14.102
Iridium- and Rhodium-Catalyzed Directed C–H Heteroarylation of Benzaldehydes with Benziodoxolone Hypervalent Iodine Reagents
Organic Letters
2018-02-21
Vol. 20 , p. 1473-1476.DOI : 10.1021/acs.orglett.8b00337
Lewis Acid Catalyzed Enantioselective Desymmetrization of Donor-Acceptor Meso-Diaminocyclopropanes
Angewandte Chemie, International Edition
2018-02-20
Vol. 57 , p. 5120-5123.DOI : 10.1002/anie.201800494
Fine-Tuned Organic Photoredox Catalysts for Fragmentation-Alkynylation Cascades of Cyclic Oxime Ethers
Chemical Science
2018-05-30
Vol. 9 , p. 5883-5889.DOI : 10.1039/C8SC01818A
2017
Bench-Stable Electrophilic Indole and Pyrrole Reagents: Serendipitous Discovery and Use in C–H Functionalization
Helvetica Chimica Acta
2017-10-30
Vol. 100 , p. e1700221.DOI : 10.1002/hlca.201700221
Dearomatization of electron poor six-membered N-heterocycles through [3+2] annulation with aminocyclopropanes
Chemical Science
2017
Vol. 8 , num. 10, p. 7112-7118.DOI : 10.1039/c7sc03197a
Indole- and Pyrrole-BX: Bench-Stable Hypervalent Iodine Reagents for Heterocycle Umpolung
Chemistry-A European Journal
2017
Vol. 23 , num. 59, p. 14702-14706.DOI : 10.1002/chem.201703723
Gold-catalyzed domino cyclization-alkynylation reactions with EBX reagents: new insights into the reaction mechanism
Dalton Transactions
2017
Vol. 46 , num. 36, p. 12257-12262.DOI : 10.1039/c7dt03154h
Enantioselective Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds
Journal Of The American Chemical Society
2017
Vol. 139 , num. 25, p. 8420-8423.DOI : 10.1021/jacs.7b04756
Palladium-Catalyzed Carboamination of Allylic Alcohols Using a Trifluoroacetaldehyde-Derived Tether
Organic Letters
2017
Vol. 19 , num. 13, p. 3548-3551.DOI : 10.1021/acs.orglett.7b01524
Divergent Access to (1,1) and (1,2)-Azidolactones from Alkenes using Hypervalent Iodine Reagents
Chemistry-A European Journal
2017
Vol. 23 , num. 40, p. 9501-9504.DOI : 10.1002/chem.201702599
Decarboxylative Alkynylation and Cyanation of Carboxylic Acids using Photoredox Catalysis and Hypervalent Iodine Reagents
Chimia
2017
Vol. 71 , num. 4, p. 226-230.DOI : 10.2533/chimia.2017.226
Room temperature decarboxylative cyanation of carboxylic acids using photoredox catalysis and cyanobenziodoxolones: a divergent mechanism compared to alkynylation
Chemical Science
2017
Vol. 8 , num. 3, p. 1790-1800.DOI : 10.1039/c6sc04907a
Heterotetracenes: Flexible Synthesis and in Silico Assessment of the Hole Transport Properties
Chemistry A European Journal
2017
Vol. 23 , num. 33, p. 8058-8065.DOI : 10.1002/chem.201701139
2016
One-Pot Three-Component Synthesis of Vicinal Diamines via In Situ Aminal Formation and Carboamination
Angewandte Chemie-International Edition
2016
Vol. 55 , num. 41, p. 12881-12885.DOI : 10.1002/anie.201607318
Divergent Reactivity of Thioalkynes in Lewis Acid Catalyzed Annulations with Donor-Acceptor Cyclopropanes
Chemistry-A European Journal
2016
Vol. 22 , num. 34, p. 11997-12001.DOI : 10.1002/chem.201602755
Nucleoside Analogues: Synthesis from Strained Rings
Israel Journal Of Chemistry
2016
Vol. 56 , num. 6-7, p. 566-577.DOI : 10.1002/ijch.201500090
Ethynyl benziodoxolones: functional terminators for cell-penetrating poly(disulfide)s
Polymer Chemistry
2016
Vol. 7 , num. 20, p. 3465-3470.DOI : 10.1039/c6py00562d
Gold-catalyzed direct alkynylation of tryptophan in peptides using TIPS-EBX
Beilstein Journal Of Organic Chemistry
2016
Vol. 12 , p. 745-749.DOI : 10.3762/bjoc.12.74
Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds with Hypervalent Iodine Reagents
Journal Of The American Chemical Society
2016
Vol. 138 , num. 7, p. 2190-2193.DOI : 10.1021/jacs.6b00278
Alkynylation of Thiols with Ethynylbenziodoxolone (EBX) Reagents: alpha- or beta- pi-Addition?
Organic Letters
2016
Vol. 18 , num. 1, p. 60-63.DOI : 10.1021/acs.orglett.5b03241
2015
Enantioselective Synthesis of Homoallylic Azides and Nitriles via Palladium-Catalyzed Decarboxylative Allylation
Organic Letters
2015
Vol. 17 , num. 23, p. 5832-5835.DOI : 10.1021/acs.orglett.5b03002
Room-Temperature Decarboxylative Alkynylation of Carboxylic Acids Using Photoredox Catalysis and EBX Reagents
Angewandte Chemie-International Edition
2015
Vol. 54 , num. 38, p. 11200-11204.DOI : 10.1002/anie.201505111
Platinum-Catalyzed Domino Reactionwith Benziodoxole Reagents for Accessing Benzene-Alkynylated Indoles
Angewandte Chemie-International Edition
2015
Vol. 54 , num. 18, p. 5438-5442.DOI : 10.1002/anie.201412321
Cyclic Hypervalent Iodine Reagents and Iron Catalysts: The Winning Team for Late-Stage C-H Azidation
Angewandte Chemie-International Edition
2015
Vol. 54 , num. 18, p. 5290-5292.DOI : 10.1002/anie.201501666
In the Lab Combining Catalyst and Reagent Design for Electrophilic Alkynylation Johnson Matthey Technology Review features new laboratory research
Johnson Matthey Technology Review
2015
Vol. 59 , num. 3, p. 284-286.DOI : 10.1595/205651315X688587
Intramolecular palladium-catalyzed alkene carboalkynylation
Tetrahedron
2015
Vol. 71 , num. 35, p. 5959-5964.DOI : 10.1016/j.tet.2015.06.030
Proteome-Wide Profiling of Targets of Cysteine reactive Small Molecules by Using Ethynyl Benziodoxolone Reagents
Angewandte Chemie-International Edition
2015
Vol. 54 , num. 37, p. 10852-10857.DOI : 10.1002/anie.201505641
1-Alkynyltriazenes as Functional Analogues of Ynamides
Angewandte Chemie -International Edition in English-
2015
Vol. 54 , p. 13393-13396.DOI : 10.1002/anie.201507033
General and Practical Formation of Thiocyanates from Thiols
Chemistry-A European Journal
2015
Vol. 21 , num. 6, p. 2662-2668.DOI : 10.1002/chem.201406171
One-Pot, Three-Component Arylalkynyl Sulfone Synthesis
Organic Letters
2015
Vol. 17 , num. 3, p. 736-739.DOI : 10.1021/acs.orglett.5b00015
Palladium-Catalyzed Vicinal Amino Alcohols Synthesis from Allyl Amines by In Situ Tether Formation and Carboetherification
Angewandte Chemie-International Edition
2015
Vol. 54 , num. 17, p. 5250-5254.DOI : 10.1002/anie.201500636
[4+2]-Annulations of Aminocyclobutanes
Organic Letters
2015
Vol. 17 , num. 4, p. 1030-1033.DOI : 10.1021/acs.orglett.5b00149
2014
Fast and Highly Chemoselective Alkynylation of Thiols with Hypervalent Iodine Reagents Enabled through a Low Energy Barrier Concerted Mechanism
Journal Of The American Chemical Society
2014
Vol. 136 , num. 47, p. 16563-16573.DOI : 10.1021/ja5083014
Enantioselective Synthesis of Polycyclic Carbocycles via an Alkynylation-Allylation-Cyclization Strategy
Organic Letters
2014
Vol. 16 , num. 21, p. 5768-5771.DOI : 10.1021/ol5028333
Diester-Substituted Aminocyclopropanes: Synthesis and Use in [3+2]-Annulation Reactions
Synlett
2014
Vol. 25 , num. 16, p. 2285-2288.DOI : 10.1055/s-0034-1378512
Room temperature alkynylation of H-phosphi(na)tes and secondary phosphine oxides with ethynylbenziodoxolone (EBX) reagents
Chemical Communications
2014
Vol. 50 , num. 85, p. 12923-12926.DOI : 10.1039/c4cc06851c
Cyclization and annulation reactions of nitrogen-substituted cyclopropanes and cyclobutanes
Chemical Communications
2014
Vol. 50 , num. 75, p. 10912-10928.DOI : 10.1039/c4cc03194f
Synthesis of (Carbo) nucleoside Analogues by [3+2] Annulation of Aminocyclopropanes
Angewandte Chemie-International Edition
2014
Vol. 53 , num. 32, p. 8484-8487.DOI : 10.1002/anie.201404832
Dynamic Kinetic Asymmetric [3+2] Annulation Reactions of Aminocyclopropanes
Journal Of The American Chemical Society
2014
Vol. 136 , num. 17, p. 6239-6242.DOI : 10.1021/ja5024578
2013
Total Synthesis and Biological Evaluation of Jerantinine E
Angewandte Chemie -International Edition in English-
2013
Vol. 52 , num. 50, p. 13373-13376.DOI : 10.1002/anie.201305533
Gold-Catalyzed Regioselective Synthesis of 2- and 3-Alkynyl Furans
Angewandte Chemie-International Edition
2013
Vol. 52 , num. 26, p. 6743-6747.DOI : 10.1002/anie.201302210
A Highly Chemoselective and Practical Alkynylation of Thiols
Journal Of The American Chemical Society
2013
Vol. 135 , num. 26, p. 9620-9623.DOI : 10.1021/ja4044196
Azidation of beta-Keto Esters and Silyl Enol Ethers with a Benziodoxole Reagent
Organic Letters
2013
Vol. 15 , num. 13, p. 3246-3249.DOI : 10.1021/ol401229v
Catalytic Friedel-Crafts Reaction of Aminocyclopropanes
Organic Letters
2013
Vol. 15 , num. 14, p. 3738-3741.DOI : 10.1021/ol401616a
Synthesis of Aminocyclobutanes by Iron-Catalyzed [2+2] Cycloaddition
Angewandte Chemie-International Edition
2013
Vol. 52 , num. 34, p. 9009-9013.DOI : 10.1002/anie.201303803
Zinc-gold cooperative catalysis for the direct alkynylation of benzofurans
Beilstein Journal Of Organic Chemistry
2013
Vol. 9 , p. 1763-1767.DOI : 10.3762/bjoc.9.204
Pd(0)-Catalyzed Alkene Oxy- and Aminoalkynylation with Aliphatic Bromoacetylenes
Journal Of Organic Chemistry
2013
Vol. 78 , num. 8, p. 3783-3801.DOI : 10.1021/jo400254q
Ethynylbenziodoxolones (EBX) as Reagents for the Ethynylation of Stabilized Enolates
Advanced Synthesis & Catalysis
2013
Vol. 355 , num. 8, p. 1631-1639.DOI : 10.1002/adsc.201300266
C2-Selective Direct Alkynylation of Indoles
Organic Letters
2013
Vol. 15 , num. 1, p. 112-115.DOI : 10.1021/ol3031389
2012
Ethynyl Benziodoxolones for the Direct Alkynylation of Heterocycles: Structural Requirement, Improved Procedure for Pyrroles, and Insights into the Mechanism
Chemistry-A European Journal
2012
Vol. 18 , p. 5655-5666.DOI : 10.1002/chem.201200200
Synthesis of 1-[(Triisopropylsilyl)ethynyl]-1 lambda(3),2-benziodoxol-3(1H)-one and Alkynylation of Indoles, Thiophenes, and Anilines
Synthesis-Stuttgart
2012
Vol. 44 , p. 1155-1158.DOI : 10.1055/s-0031-1290589
Catalytic Enantiospecific [3+2] Annulation of Aminocyclopropanes with Ketones
Chemistry-A European Journal
2012
Vol. 18 , p. 4844-4849.DOI : 10.1002/chem.201103971
Para-Selective Gold-Catalyzed Direct Alkynylation of Anilines
Organic Letters
2012
Vol. 14 , p. 744-747.DOI : 10.1021/ol203289v
Iron-Catalyzed [3+2] Annulation of Aminocyclopropanes with Aldehydes: Stereoselective Synthesis of Aminotetrahydrofurans
Organic Letters
2012
Vol. 14 , p. 386-389.DOI : 10.1021/ol203144v
2011
Formal Homo-Nazarov and Other Cyclization Reactions of Activated Cyclopropanes
Chemistry – A European Journal
2011
Vol. 17 , num. 51, p. 14527-14538.DOI : 10.1002/chem.201102583
Catalytic [3+2] Annulation of Aminocyclopropanes for the Enantiospecific Synthesis of Cyclopentylamines
Angewandte Chemie, International Edition
2011
Vol. 50 , num. 50, p. 12075-12079.DOI : 10.1002/anie.201106255
Benziodoxole-based hypervalent iodine reagents for atom-transfer reactions
Chemical Communications
2011
Vol. 47 , p. 102-115.DOI : 10.1039/c0cc02265a
One-pot gold-catalyzed synthesis of 3-silylethynyl indoles from unprotected o-alkynylanilines
Beilstein Journal Of Organic Chemistry
2011
Vol. 7 , p. 565-569.DOI : 10.3762/bjoc.7.65
Cyclopropanes and Hypervalent Iodine Reagents: High Energy Compounds for Applications in Synthesis and Catalysis
Chimia
2011
Vol. 65 , p. 649-651.DOI : 10.2533/chimia.2011.649
Pd(0)-Catalyzed Oxy- and Aminoalkynylation of Olefins for the Synthesis of Tetrahydrofurans and Pyrrolidines
Organic Letters
2011
Vol. 13 , p. 6324-6327.DOI : 10.1021/ol2029383
A Palladium-Catalyzed Aminoalkynylation Strategy towards Bicyclic Heterocycles: Synthesis of (±)-Trachelanthamidine
Angewandte Chemie, International Edition
2011
Vol. 50 , num. 20, p. 4680-4683.DOI : 10.1002/anie.201100718
2010
Direct Alkynylation of Thiophenes: Cooperative Activation of TIPS–EBX with Gold and Brønsted Acids
Angewandte Chemie, International Edition
2010
Vol. 49 , num. 40, p. 7304-7307.DOI : 10.1002/anie.201003179
Ethynyl-1,2-benziodoxol-3(1 H)-one (EBX): An Exceptional Reagent for the Ethynylation of Keto, Cyano, and Nitro Esters
Chemistry, A European Journal
2010
Vol. 16 , num. 31, p. 9457-9461.DOI : 10.1002/chem.201001539
Catalytic Selective Cyclizations of Aminocyclopropanes: Formal Synthesis of Aspidospermidine and Total Synthesis of Goniomitine
Angewandte Chemie, International Edition
2010
Vol. 49 , p. 5767-5770.DOI : 10.1002/anie.201001853
Synthesis of Chiral Bifunctional (Thio)Urea N-Heterocyclic Carbenes
Synlett
2010
p. 881-884.DOI : 10.1055/s-0029-1219543
Pd-Catalyzed Intramolecular Oxyalkynylation of Alkenes with Hypervalent Iodine
Organic Letters
2010
Vol. 12 , num. 2, p. 384-387.DOI : 10.1021/ol9027286
2009
Direct Alkynylation of Indole and Pyrrole Heterocycles
Angewandte Chemie, International Edition
2009
Vol. 48 , num. 49, p. 9346-9349.DOI : 10.1002/anie.200905419
Catalytic Formal Homo-Nazarov Cyclization
Organic Letters
2009
Vol. 11 , num. 4, p. 1023-1026.DOI : 10.1021/ol802970g
2008
Total Synthesis of (-)-Pseudolaric Acid B
Journal of the American Chemical Society
2008
Vol. 130 , num. 48, p. 16424-16434.DOI : 10.1021/ja806724x
2007
Cobalt-Catalyzed Synthesis of Tertiary Azides from α,α-Disubstituted Olefins under Mild Conditions Using Commercially Available Reagents
Synthesis
2007
num. 24, p. 3839-3845.DOI : 10.1055/s-2007-1000817
Total synthesis of (-)-pseudolaric Acid B
Journal of the American Chemical Society
2007
Vol. 129 , num. 47, p. 14556-7.DOI : 10.1021/ja076165q
2006
Hydrazines and Azides via the Metal-Catalyzed Hydrohydrazination and Hydroazidation of Olefins
Journal of the American Chemical Society
2006
Vol. 128 , num. 35, p. 11693-11712.DOI : 10.1021/ja062355+
2005
Cobalt-Catalyzed Hydrohydrazination of Dienes and Enynes: Access to Allylic and Propargylic Hydrazides
Organic Letters
2005
Vol. 7 , num. 19, p. 4249-4252.DOI : 10.1021/ol0517473
Cobalt-Catalyzed Hydroazidation of Olefins: Convenient Access to Alkyl Azides
Journal of the American Chemical Society
2005
Vol. 127 , num. 23, p. 8294-8295.DOI : 10.1021/ja052164r
2004
Alkene hydrazination: Catalytic hydrohydrazination of a wide range of alkenes with a simple Mn complex
Angewandte Chemie, International Edition
2004
Vol. 43 , num. 31, p. 4099-4102.DOI : 10.1002/anie.200460811
Convenient synthesis of alkylhydrazides by the cobalt-catalyzed hydrohydrazination reaction of olefins and azodicarboxylates
Journal of the American Chemical Society
2004
Vol. 126 , num. 18, p. 5676-5677.DOI : 10.1021/ja048698u
2001
Synthetic process development and scale up of palladium-catalyzed alkoxycarbonylation of chloropyridines
Organic Process Research & Development
2001
Vol. 5 , num. 6, p. 572-574.DOI : 10.1021/op010012k
Reviews
2023
X-Ray and NMR Structural Data of Ethynylbenziodoxolones (EBXs) Reagents and Their Analogues
Helvetica Chimica Acta
2023-02-14
DOI : 10.1002/hlca.202200175
Recent progress in alkynylation with hypervalent iodine reagents
Chemical Communications
2023-01-19
DOI : 10.1039/d2cc06168f
2022
Pd-catalyzed functionalization of alkenes and alkynes using removable tethers
Tetrahedron
2022-11-05
Vol. 128 , p. 133135.DOI : 10.1016/j.tet.2022.133135
Azidation with Hypervalent Iodine Reagents
Synthesis
2022-11-23
DOI : 10.1055/a-1966-4974
Activation of aminocyclopropanes via radical intermediates
Chemical Society Reviews
2022-08-08
Vol. 51 , p. 7344-7357.DOI : 10.1039/d2cs00090c
Radical Alkynylations with EthynylBenziodoXolones: From Photocatalysis to Direct Excitation
Chimia
2022-04-01
Vol. 76 , num. 4, p. 312-315.DOI : 10.2533/chimia.2022.312
Hypervalent Iodine-Mediated Late-Stage Peptide and Protein Functionalization
Angewandte Chemie-International Edition
2022
Vol. 61 , num. 7, p. e202112287.DOI : 10.1002/anie.202112287
2021
Umpolung Of Electron-Rich Heteroarenes With Hypervalent Iodine Reagents
Heterocycles
2021-01-01
Vol. 103 , num. 2, p. 555-591.DOI : 10.3987/COM-20-S(K)33
Catalytic Enantioselective Ring-Opening Reactions of Cyclopropanes
Chemical Reviews
2021
Vol. 121 , num. 1, p. 227–263.DOI : 10.1021/acs.chemrev.0c00109
2020
Palladium-Catalyzed Functionalization of Olefins and Alkynes: From Oxyalkynylation to Tethered Dynamic Kinetic Asymmetric Transformations (DYKAT)
Synlett
2020-11-10
Vol. 32 , p. 472-487.DOI : 10.1055/a-1308-0021
Vinylbenziodoxol(on)es: Synthetic Methods and Applications
Helvetica Chimica Acta
2020-10-30
Vol. 103 , p. e2000191.DOI : 10.1002/hlca.202000191
Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis
Beilstein Journal Of Organic Chemistry
2020-05-29
Vol. 16 , p. 1163-1187.DOI : 10.3762/bjoc.16.103
2018
Cyclic Hypervalent Iodine Reagents: Enabling Tools for Bond Disconnection via Reactivity Umpolung
Accounts of Chemical Research
2018-11-28
Vol. 51 , num. 12, p. 3212-3225.DOI : 10.1021/acs.accounts.8b00468
2017
In situ tether formation from amines and alcohols enabling highly selective Tsuji-Trost allylation and olefin functionalization
Chemical Science
2017
Vol. 8 , num. 1, p. 32-39.DOI : 10.1039/c6sc04366f
2016
Benziodoxol(on)e Reagents as Tools in Organic Synthesis: The Background behind the Discovery at the Laboratory of Catalysis and Organic Synthesis
Synlett
2016
Vol. 27 , num. 20, p. 2761-2773.DOI : 10.1055/s-0036-1589409
Cyclic Hypervalent Iodine Reagents for Atom-Transfer Reactions: Beyond Trifluoromethylation
Angewandte Chemie-International Edition
2016
Vol. 55 , num. 14, p. 4436-4454.DOI : 10.1002/anie.201509073
2014
Taming Hypervalent Bonds and Strained Rings for Catalysis and Synthesis
Chimia
2014
Vol. 68 , num. 7-8, p. 516-521.DOI : 10.2533/chimia.2014.516
2013
Gold-Catalyzed Alkynylation: Acetylene-Transfer instead of Functionalization
Israel Journal Of Chemistry
2013
Vol. 53 , num. 11-12, p. 901-910.DOI : 10.1002/ijch.201300044
2012
Asymmetric Organocatalysis Meets Hypervalent Iodine Chemistry for the alpha-Functionalization of Carbonyl Compounds
Chemcatchem
2012
Vol. 4 , p. 955-958.DOI : 10.1002/cctc.201200116
Indole Alkaloids Synthesis via a Selective Cyclization of Aminocyclopropanes
Chimia
2012
Vol. 66 , p. 233-236.DOI : 10.2533/chimia.2012.233
Electrophilic alkynylation: the dark side of acetylene chemistry
Chemical Society Reviews
2012
Vol. 41 , p. 4165-4179.DOI : 10.1039/c2cs35034c
2011
Cyclization of Aminocyclopropanes in Indole Alkaloids Synthesis
Synlett
2011
num. 5, p. 589-593.DOI : 10.1055/s-0030-1259553
Benziodoxole-based hypervalent iodine reagents for atom-transfer reactions
Chemical Communications- Royal Society of Chemistry
2011
Vol. 47 , p. 102-115.DOI : 10.1039/C0CC02265A
2009
Cyclization and Cycloaddition Reactions of Cyclopropyl Carbonyls and Imines
Synthesis
2009
num. 20, p. 3353-3374.DOI : 10.1055/s-0029-1216998
Cyclization of Cyclopropyl Carbonyls and the Homo-Nazarov Reaction
Chimia
2009
Vol. 63 , num. 3, p. 162-167.DOI : 10.2533/chimia.2009.162
Theses
2024
Novel Alkynylation Methods through the Combination of Hypervalent Iodine Reagents and Alkynyl-trifluoroborate Salts
Lausanne: EPFL2024
p. 292.DOI : 10.5075/epfl-thesis-10492
2023
Chemodivergent Asymmetric Synthesis via Catalytically Formed Chiral Auxiliary
Lausanne: EPFL2023
p. 338.DOI : 10.5075/epfl-thesis-10493
Synthesis and application of bifunctional hypervalent iodine reagents for peptide modification.
Lausanne: EPFL2023
p. 162.DOI : 10.5075/epfl-thesis-10148
Development of Hetero-Vinylbenziodoxolone Reagents for Applications in Synthetic Methodology and Biomolecule Functionalization
Lausanne: EPFL2023
p. 213.DOI : 10.5075/epfl-thesis-9953
Hypervalent Iodine: New Reagents and Functionalization of Peptides
Lausanne: EPFL2023
p. 314.DOI : 10.5075/epfl-thesis-9978
2022
Photochemical Alkynylations with Hypervalent Iodine Reagents
Lausanne: EPFL2022
p. 190.DOI : 10.5075/epfl-thesis-9481
Rh-catalyzed C-H Bond Heteroarylation with Hypervalent Iodine Reagents and Pd-Catalyzed Tethered Functionalizations of Carbon-Carbon Multiple Bonds.
Lausanne: EPFL2022
p. 476.DOI : 10.5075/epfl-thesis-9235
Ring-Opening Reactions of Aminocyclopropanes and Aminocyclobutanes
Lausanne: EPFL2022
p. 264.DOI : 10.5075/epfl-thesis-9169
Azide-Containing Hypervalent Iodine Reagents for Biomolecules Functionalization
Lausanne: EPFL2022
p. 422.DOI : 10.5075/epfl-thesis-9197
2021
New Vinylation and Alkynylation Strategies with Hypervalent Iodine Reagents and Diazo Compounds
Lausanne: EPFL2021
p. 413.DOI : 10.5075/epfl-thesis-8727
New Strategies for the Functionalization of Alkenes Exploiting Tethering Chemistry and Ring Strain
Lausanne: EPFL2021
p. 385.DOI : 10.5075/epfl-thesis-8306
2020
Development of Photocatalysts towards the Visible-Light driven C-Terminal Bioconjugation of Peptides and Proteins
Lausanne: EPFL2020
p. 382.DOI : 10.5075/epfl-thesis-10420
Palladium Catalysed Intramolecular Carbo-oxygenation of Propargylic Amines to Access 1,2-Amino Alcohols and alpha-Amino Ketones via in situ Tether Formation
Lausanne: EPFL2020
p. 310.DOI : 10.5075/epfl-thesis-7462
2019
Development of New Strategies of Umpolung with Cyclic Hypervalent Iodine Reagents
Lausanne: EPFL2019
p. 598.DOI : 10.5075/epfl-thesis-9502
Photoredox-Catalyzed Decarboxylation for the Transfer of Alkynes and Nitriles Using Hypervalent Iodine Reagents
Lausanne: EPFL2019
p. 448.DOI : 10.5075/epfl-thesis-9212
Application of Hypervalent Iodine Reagents for Novel Cysteine Labeling
Lausanne: EPFL2019
p. 443.DOI : 10.5075/epfl-thesis-9119
2018
Developing Reactions of Strained Rings
Lausanne: EPFL2018
p. 332.DOI : 10.5075/epfl-thesis-8579
2017
In Situ Tethering Strategies for the 3-Component Synthesis of Vicinal Amino Alcohols and Diamines via Pd-Catalyzed Carboetherification and Carboamination
Lausanne: EPFL2017
p. 328.DOI : 10.5075/epfl-thesis-7319
2016
Lewis acid Catalyzed Annulations of Donor-Acceptor Aminocyclopropanes and Aminocyclobutanes
Lausanne: EPFL2016
p. 478.DOI : 10.5075/epfl-thesis-7199
Synthesis of Alkynylated Heterocycles by Direct C-H Alkynylation or Domino Alkynylation Reactions
Lausanne: EPFL2016
p. 356.DOI : 10.5075/epfl-thesis-6915
2015
Cyclic Hypervalent Iodine Reagents and Pd-Catalysis
Lausanne: EPFL2015
p. 846.DOI : 10.5075/epfl-thesis-6624
2014
Synthesis and Reactivity of Donor-Acceptor Substituted Aminocyclopropanes and Aminocyclobutanes
Lausanne: EPFL2014
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2013
Pd-Catalyzed Oxy- and Aminoalkynylation of Olefins
Lausanne: EPFL2013
DOI : 10.5075/epfl-thesis-5620
2012
Development of Catalytic Umpolung
Lausanne: EPFL2012
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Catalytic Formal Homo-Nazarov Reaction and Other Cyclizations of Cyclopropanes
Lausanne: EPFL2012
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2011
New Acetylene Chemistry
Lausanne: EPFL2011
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Book Chapters
2020
1‐Azido‐3,3‐dimethyl‐3‐(1H )‐1,2‐benziodoxole
Encyclopedia of Reagents for Organic Synthesis; Wiley, 2020-05-04.ISBN : 9780470842898
DOI : 10.1002/047084289X.rn02312
2019
Silyl Ethynyl Benziodoxolone Reagents
Encyclopedia of Reagents for Organic Synthesis; Wiley, 2019-04-01.ISBN : 9780470842898
DOI : 10.1002/047084289X.rn01503.pub2
2018
Alkynylations and Vinylations
PATAI’S Chemistry of Functional Groups; Wiley, 2018-06-13. p. 1-58.DOI : 10.1002/9780470682531.pat0951
2015
Alkynylation with Hypervalent Iodine Reagents
Hypervalent Iodine Chemistry; Springer Verlag, 2015. p. 187-222.ISBN : 978-3-319-33733-3
DOI : 10.1007/128_2015_660
2013
Synthesis of Saturated Heterocycles via Metal-Catalyzed Formal Cycloaddition Reactions That Generate a C–N or C–O Bond
Synthesis of Heterocycles via Metal-Catalyzed Reactions that Generate One or More Carbon-Heteroatom Bonds; Berlin Heidelberg: Springer Verlag, 2013. p. 225-270.ISBN : 978-3-642-38879-8
DOI : 10.1007/7081_2013_108
2012
Silyl Ethynyl Benziodoxolone Reagents
Encyclopedia of Reagents for Organic Synthesis; Wiley, 2012-09-14.ISBN : 9780470842898
DOI : 10.1002/047084289X.rn01503
2010
Azides by Olefin Hydroazidation Reactions
Organic Azides: Syntheses and Applications; Wiley, 2010. p. 95-112.DOI : 10.1002/9780470682517.ch4