Blue light-sheet-assisted two-photon polymerization

Project Description

Photopolymerization is a light-based additive manufacturing (AM) technique that facilitates the fabrication of complex three-dimensional (3D) structures quickly and cost-effectively. One-photon polymerization allows printing with high speed despite its limited resolution. In contrast, two-photon polymerization (2PP) offers sub-micrometer precision at the cost of slower throughput.

We propose a method combining 2PP and one-photon absorption (1PA) to get the advantages of the dual capabilities, allowing for faster printing while preserving high resolution and enhancing depth sectioning. In this study, we employ a CW laser beam at 405 nm to pre-excite a photocurable resin for rapidly reaching the polymerization threshold by 1PA and a tightly focused femtosecond (fs) laser beam at 780 nm to provide the missing energy for surpassing the threshold and solidifying the resin through two-photon absorption. The material is only polymerized at the intersection volume of two light sources. This sequential dual-excitation approach alters the voxel growth kinetics, reducing the polymerization threshold and accelerating the voxel growth.

Blue light-sheet-assisted two-photon polymerization for printing 3D structures.
Schematic illustration of the experimental setup. SEM image of the printed bridge by only 2PP and blue light-sheet assisted 2PP. The scale bars are 5 𝜇m [1].

Objectives
• Optimize the dual-beam printing systems, synchronization, and spatial overlap
• Design and fabricate 3D microstructures to benchmark speed, resolution, and fidelity improvements
• Study the influence of pre-sensitization on voxel growth and polymerization dynamics
• (Optional) Extend the system to functional materials or biocompatible resins for applications in photonics, microrobotics, or tissue engineering

🧩 Candidate Profile
We’re looking for someone who is curious, hands-on, and eager to learn!
• Background in optics, photonics, physics, or materials science
• Hands-on experience in laser systems or optical alignment (not mandatory – preferred)
• Programming skills (e.g., Python, MATLAB, Solidworks) for data analysis and experiment automation
• Interest in microfabrication, light-matter interaction, or additive manufacturing

📚 You’ll Learn
• Advanced light-based additive manufacturing techniques, both single- and two-photon polymerization
• Optical setup design, alignment and laser-matter interaction principles
• Microfabrication workflows and high-resolution imaging (SEM)
• Scientific communication and reporting
• Potential to contribute to a high-impact journal publication or conference presentation
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📬 To apply, send an email to [email protected]. Informal questions and lab visits are very welcome!

References
[1] B. Unlu, M.I. Álvarez-Castaño, A. Boniface, Y. Pu, C. Moser, Single-photon-assisted two-photon polymerization, Addit. Manuf. 94 (2024) 104455. https://doi.org/10.1016/j.addma.2024.104455.