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Journal Articles

2024

The isotopic signature of U(V) during bacterial reduction

A. Brown; M. Molinas; Y. Roebbert; R. Faizova; T. Vitova et al.

Geochemical Perspectives Letters

2024-04-09

Vol. 29 , p. 45-50.

DOI : 10.7185/geochemlet.2411

Journal Articles

2024

The isotopic signature of U(V) during bacterial reduction

Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides

Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state

Two-Electron Redox Reactivity of Thorium Supported by Redox-Active Tripodal Frameworks

Accessing a Highly Reducing Uranium(III) Complex through Cyclometalation

A trinuclear metallasilsesquioxane of uranium(III)

2023

Multimetallic Uranium Nitride Cubane Clusters from Dinitrogen Cleavage

Dinitrogen cleavage by a dinuclear uranium(III) complex

Multielectron Redox Chemistry of Uranium by Accessing the plus II Oxidation State and Enabling Reduction to a U(I) Synthon

Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids

Isolation and redox reactivity of cerium complexes in four redox states

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

Bonding and Reactivity in Terminal versus Bridging Arenide Complexes of Thorium Acting as Th II Synthons

2022

Assembling diuranium complexes in different states of charge with a bridging redox-active ligand

The mechanism of Fe induced bond stability of uranyl(v)

Cation assisted binding and cleavage of dinitrogen by uranium complexes

Nitrogen activation and cleavage by a multimetallic uranium complex

Design Principles for the Development of Gd(III) Polarizing Agents for Magic Angle Spinning Dynamic Nuclear Polarization

Structure and Reactivity of Polynuclear Divalent Lanthanide Disiloxanediolate Complexes br

Multi-electron Transfer by U(II) and Masked U(II) Complexes

Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer

Reactivity of Multimetallic Thorium Nitrides Generated by Reduction of Thorium Azides

Gd3+-Functionalized Lithium Niobate Nanoparticles for Dual Multiphoton and Magnetic Resonance Bioimaging

Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides

2021

Nitride protonation and NH3 binding versus N-H bond cleavage in uranium nitrides

Stepwise Reduction of Dinitrogen by a Uranium-Potassium Complex Yielding a U(VI)/U(IV) Tetranitride Cluster

Synthesis, structure, and reactivity of uranium(VI) nitrides

Single metal four-electron reduction by U(II) and masked “U(II)” compounds

Synthesis and Characterization of Water Stable Uranyl(V) Complexes

Biological reduction of a U(V)-organic ligand complex

Delivery of a Masked Uranium(II) by an Oxide-Bridged Diuranium(III) Complex

2020

Photochemical Synthesis of a Stable Terminal Uranium(VI) Nitride

Carbon dioxide reduction by lanthanide(iii) complexes supported by redox-active Schiff base ligands

Structure and small molecule activation reactivity of a metallasilsesquioxane of divalent ytterbium

Carbon Dioxide Reduction by Multimetallic Uranium(IV) Complexes Supported by Redox-Active Schiff Base Ligands

Assembly of High-Spin [Fe-3] Clusters by Ligand-Based Multielectron Reduction

Accessing the plus IV Oxidation State in Molecular Complexes of Praseodymium

Ligand-Supported Facile Conversion of Uranyl(VI) into Uranium(IV) in Organic and Aqueous Media

C-H Bond Activation by an Isolated Dinuclear U(III)/U(IV) Nitride

Anhydrous Conditions Enable the Catalyst-Free Carboxylation of Aromatic Alkynes with CO2 under Mild Conditions

Stabilization of the Oxidation State plus IV in Siloxide-Supported Terbium Compounds

2019

Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands

Theoretical Investigation of the Electronic Structure and Magnetic Properties of Oxo-Bridged Uranyl(V) Dinuclear and Trinuclear Complexes

Molecular Complex of Tb in the +4 Oxidation State

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride

A Factor Two Improvement in High-Field Dynamic Nuclear Polarization from Gd(III) Complexes by Design

Correction: Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex (vol 10, pg 3543, 2019)

Structural Snapshots of Cluster Growth from {U6 } to {U38 } During the Hydrolysis of UCl4

Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex

CS2 Reductive Coupling to Acetylenedithiolate by a Dinuclear Ytterbium(II) Complex

A complete series of uranium(iv) complexes with terminal hydrochalcogenido (EH) and chalcogenido (E) ligands E = O, S, Se, Te

Carbon dioxide reduction by dinuclear Yb(ii) and Sm(ii) complexes supported by siloxide ligands

The role of bridging ligands in dinitrogen reduction and functionalization by uranium multimetallic complexes

2018

The effect of iron binding on uranyl(V) stability

A tetranuclear samarium(II) inverse sandwich from direct reduction of toluene by a samarium(II) siloxide

Four-electron Reduction and Functionalization of N₂ by a Uranium(III) Bridging Nitride

Reversible Dihydrogen Activation and Hydride Transfer by a Uranium Nitride Complex

The secret is in the ring

Synthesis and Characterization of a Water Stable Uranyl(V) Complex

2017

Reduction of a Cerium(III) Siloxide Complex To Afford a Quadruple-Decker Arene-Bridged Cerium(II) Sandwich

A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand framework

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

Nitrogen reduction and functionalization by a multimetallic uranium nitride complex

Ligand and Metal Based Multielectron Redox Chemistry of Cobalt Supported by Tetradentate Schiff Bases

CO Cleavage and CO2 Functionalization under Mild Conditions by a Multimetallic CsU2 Nitride Complex

Synthesis and SMM behaviour of trinuclear versus dinuclear 3d-5f uranyl(v)-cobalt(II) cation-cation complexes

2016

Isolation of a Star-Shaped Uranium(V/VI) Cluster from the Anaerobic Photochemical Reduction of Uranyl(VI)

Facile CO Cleavage by a Multimetallic CsU2 Nitride Complex

Enhancement of silicon solar cells by downshifting with Eu and Tb coordination complexes

Uranium(IV) Terminal Hydrosulfido and Sulfido Complexes: The Nature of the Uranium–Sulfur Bond